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Adrian B. Chaplin and Andrew S. Weller B[BOND]H Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine–Boranes Angewandte Chemie International Edition 49

Article first published online: 24 NOV 2009 | DOI: 10.1002/anie.200905185

Thumbnail image of graphical abstract

The missing link: A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine–borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine–borane activation modes within the same molecule.

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