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Anastas Sidiropoulos, Cameron Jones, Andreas Stasch, Susanne Klein and Gernot Frenking N-Heterocyclic Carbene Stabilized Digermanium(0) Angewandte Chemie International Edition 48

Article first published online: 17 NOV 2009 | DOI: 10.1002/anie.200905495

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Zero Ge! Reductions of an N-heterocyclic carbene (NHC) adduct of GeCl2 with magnesium(I) dimers afford a dimeric compound (see picture), which structural and theoretical studies show to contain a singlet digermanium(0) fragment :Ge[DOUBLE BOND]Ge: datively coordinated by two NHC ligands.

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