Gwilherm Evano, Alexis Coste and Kévin Jouvin Ynamides: Versatile Tools in Organic Synthesis Angewandte Chemie International Edition 49
A world of possibilities: Ynamides display an exceptionally fine balance between stability and reactivity, and they offer multiple opportunities for the inclusion of nitrogen-based functionalities into organic molecules (see scheme; EWG=electron-withdrawing group). Recent breakthroughs in the preparation of these substrates have revitalized interest in nitrogen-substituted alkynes. Recent developments in this area are highlighted.
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