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Christina Y. Tang, Amber L. Thompson and Simon Aldridge Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues Angewandte Chemie International Edition 49

Article first published online: 22 DEC 2009 | DOI: 10.1002/anie.200906171

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Side-on or end-on? Rhodium and iridium complexes featuring aminoboranes (R2N[DOUBLE BOND]BH2) as ligands have been synthesized and structurally characterized. Crystallographic measurements show that the ligands—in contrast to isoelectronic alkene donors—bind in an end-on fashion through a bis(σ-borane) binding motif (see structure).

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