Christina Y. Tang, Amber L. Thompson and Simon Aldridge Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues Angewandte Chemie International Edition 49
Side-on or end-on? Rhodium and iridium complexes featuring aminoboranes (R2NBH2) as ligands have been synthesized and structurally characterized. Crystallographic measurements show that the ligands—in contrast to isoelectronic alkene donors—bind in an end-on fashion through a bis(σ-borane) binding motif (see structure).
Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf