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Michael Geisler, Roland R. Netz and Thorsten Hugel Pulling a Single Polymer Molecule off a Substrate Reveals the Binding Thermodynamics of Cosolutes Angewandte Chemie International Edition 49

Article first published online: 31 MAY 2010 | DOI: 10.1002/anie.200907098

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To bind or not to bind: Cosolutes modify, or even determine, the interactions between macromolecules and surfaces. A combination of single-molecule atomic force microscopy with thermodynamic modeling allows the extraction of the binding parameters of cosolutes onto a macromolecule in solution and also in its surface-adsorbed state.

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