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Daqiang Yuan, Dan Zhao, Daofeng Sun and Hong-Cai Zhou An Isoreticular Series of Metal–Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity Angewandte Chemie International Edition 49

Article first published online: 11 JUN 2010 | DOI: 10.1002/anie.201001009

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Holding gas: One of the isoreticular metal–organic frameworks (MOFs) that have been synthesized and characterized structurally, PCN-68 (see structure), has a Langmuir surface area of as high as 6033 m2 g−1. The MOFs also display excellent gas (H2, CH4, and CO2) adsorption capacity.

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