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Christopher J. Serpell, Nathan L. Kilah, Paulo J. Costa, Vítor Félix and Paul D. Beer Halogen Bond Anion Templated Assembly of an Imidazolium Pseudorotaxane Angewandte Chemie International Edition 49

Version of Record online: 22 JUN 2010 | DOI: 10.1002/anie.201001729

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Halogen bonding has been exploited in the assembly of an interpenetrated molecular system. The strength of chloride-anion-templated pseudorotaxane formation with a 2-bromo-functionalized imidazolium threading component and an isophthalamide macrocycle (see picture) is significantly enhanced compared to hydrogen-bonded pseudorotaxane analogues.

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