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Dr. Sergio Navalon, Roberto Martin, Dr. Mercedes Alvaro and Prof. Dr. Hermenegildo Garcia Gold on Diamond Nanoparticles as a Highly Efficient Fenton Catalyst Angewandte Chemie International Edition 49

Article first published online: 28 SEP 2010 | DOI: 10.1002/anie.201003216

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Nanojewels as catalysts: Degradation of phenol with a small excess of H2O2 can be achieved by using gold nanoparticles supported on Fenton-treated diamond nanoparticles as a highly selective (at least 79 %) and efficient (turnover number: 321 000) catalyst for the Fenton reaction at room temperature. The proposed mechanism is shown schematically in the picture.

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