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Dr. Takahiro Nishimura, Yuko Maeda and Prof. Dr. Tamio Hayashi Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene–Rhodium Complexes Angewandte Chemie International Edition 49

Article first published online: 26 AUG 2010 | DOI: 10.1002/anie.201003775

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Chiral tridentate ligand: A chiral diene–rhodium complex (1; see scheme) was found to catalyze the intermolecular asymmetric cyclopropanation of alkenes with dimethyl diazomalonate to give 1,1-cyclopropane diesters in good yields and with high enantioselectivity.

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