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Shang-Da Jiang, Prof. Dr. Bing-Wu Wang, Prof. Dr. Gang Su, Prof. Dr. Zhe-Ming Wang and Prof. Dr. Song Gao A Mononuclear Dysprosium Complex Featuring Single-Molecule-Magnet Behavior Angewandte Chemie International Edition 49

Article first published online: 27 AUG 2010 | DOI: 10.1002/anie.201004027

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No dates for Dy3+: With a single-ion magnet containing dysprosium, magnetic-site dilution leads to a hysteresis loop that can be detected at 0.5 and 2 K. On cooling below 8 K, the relaxation mechanism of the undiluted complex changes from a thermally activated process to quantum tunneling. The quantum tunneling can be suppressed by applying a direct-current field and by magnetic site dilution.

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