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Xu-Fan Wang, Qiu-Lin Hua, Ying Cheng, Xiao-Lei An, Qing-Qing Yang, Dr. Jia-Rong Chen and Prof. Dr. Wen-Jing Xiao Organocatalytic Asymmetric Sulfa-Michael/Michael Addition Reactions: A Strategy for the Synthesis of Highly Substituted Chromans with a Quaternary Stereocenter Angewandte Chemie International Edition 49

Article first published online: 7 OCT 2010 | DOI: 10.1002/anie.201004534

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Simply complex: Diverse and structurally complex chroman derivatives with a quaternary stereocenter have been obtained through the titled reaction of thiols with nitroolefin enoates using the bifunctional catalyst 1. The reaction features simple experimental procedures, high yield, enantiomeric excess, and excellent diastereoselectivity.

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