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Karolina Kwapien, Dr. Marek Sierka, Dr. Jens Döbler, Prof. Dr. Joachim Sauer, Marko Haertelt, Dr. André Fielicke and Prof. Dr. Gerard Meijer Structural Diversity and Flexibility of MgO Gas-Phase Clusters Angewandte Chemie International Edition 50

Article first published online: 7 JAN 2011 | DOI: 10.1002/anie.201004617

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Working out the gas charge: Only one structure type is known for bulk MgO. In contrast, quantum chemical calculations combined with infrared multiple photon dissociation experiments demonstrate that neutral and cationic gas-phase clusters of MgO display unusual structural diversity and flexibility (see picture).

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