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Zhening Zhu, Dr. Haifeng Meng, Wenjing Liu, Xinfeng Liu, Jianxiao Gong, Prof. Xiaohui Qiu, Prof. Lei Jiang, Prof. Dan Wang and Prof. Zhiyong Tang Superstructures and SERS Properties of Gold Nanocrystals with Different Shapes Angewandte Chemie International Edition 50

Version of Record online: 5 JAN 2011 | DOI: 10.1002/anie.201005493

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Keeping in shape: The shapes of gold nanocrystals determine their self-assembly behavior—rhombic dodecahedral nanocrystals form triangular multilayers (see picture), whereas cubic and octahedral nanocrystals form monolayers or multilayers without well-defined contours. The three superstructures exhibit different optical properties, and the rhombic dodecahedral gold nanocrystals display strong anisotropic SERS effects.

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