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Dr. Christina Y. Tang, William Smith, Dr. Amber L. Thompson, Dr. Dragoslav Vidovic and Dr. Simon Aldridge Iridium-Mediated Borylation of Benzylic C[BOND]H Bonds by Borohydride Angewandte Chemie International Edition 50

Version of Record online: 29 DEC 2010 | DOI: 10.1002/anie.201006320

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Simple source: An intramolecular iridium-mediated C[BOND]H borylation proceeds through transfer of a BH3 fragment from borohydride to a benzylic carbon center (see scheme; coe=cyclooctene). Simple and inexpensive LiBH4 is thus utilized as the boron source in C[BOND]H to C[BOND]B conversion.

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