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Charles S. Yeung and Prof. Vy M. Dong A New Direction in Enantioselective Catalysis: Scaffolding Ligands in Olefin Hydroformylation Angewandte Chemie International Edition 50

Version of Record online: 17 JAN 2011 | DOI: 10.1002/anie.201006489

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A designer phosphine ligand capable of bonding covalently to an olefin substrate directed rhodium-catalyzed hydroformylation to generate branched aldehydes with high regio- and enantioselectivity. The use of such scaffolding ligands opens up new directions in asymmetric synthesis.

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