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Scott J. Hasty, Matthew A. Kleine and Prof. Dr. Alexei V. Demchenko S-Benzimidazolyl Glycosides as a Platform for Oligosaccharide Synthesis by an Active–Latent Strategy Angewandte Chemie International Edition 50

Version of Record online: 23 MAR 2011 | DOI: 10.1002/anie.201007212

Thumbnail image of graphical abstract

Doing the Biz: The S-benzimidazolyl (SBiz) anomeric moiety is a new leaving group that can be activated for glycosylation under a variety of conditions, including metal-assisted and alkylation pathways. Application of a substituted SBiz moiety (X=anisoyl, see picture) allows active–latent and armed–disarmed types of oligosaccharide assembly.

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