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Wei Wei and Prof. Dr. Jian-Xin Ji Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates Angewandte Chemie International Edition 50

Article first published online: 24 AUG 2011 | DOI: 10.1002/anie.201100219

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Direct access: The title reaction has been developed under mild reaction conditions (see scheme; DMSO=dimethyl sulfoxide). This reaction can be effectively scaled up and offers not only a green and attractive approach to β-ketophosphonates, but also a useful example of direct incorporation of an oxygen atom from dioxygen into organic frameworks.

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