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Prof. Dr. Thomas M. Klapötke, Franz A. Martin and Dr. Jörg Stierstorfer C2N14: An Energetic and Highly Sensitive Binary Azidotetrazole Angewandte Chemie International Edition 50

Version of Record online: 6 APR 2011 | DOI: 10.1002/anie.201100300

Thumbnail image of graphical abstract

7:1 to nitrogen! Diazotization and subsequent dimerization of the triaminoguanidinium cation gave 1-diazidocarbamoyl-5-azidotetrazole (see picture). The structurally and spectroscopically characterized binary CN compound shows great energetic performance and a high heat of formation, but also extremely high sensitivity to friction and shock.

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