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Bulent Baris, Vincent Luzet, Dr. Eric Duverger, Prof. Dr. Philippe Sonnet, Prof. Dr. Frank Palmino and Dr. Frederic Cherioux Robust and Open Tailored Supramolecular Networks Controlled by the Template Effect of a Silicon Surface Angewandte Chemie International Edition 50

Version of Record online: 6 APR 2011 | DOI: 10.1002/anie.201100332

Thumbnail image of graphical abstract

Fullerenes framed: The combination of molecule–molecule interactions and molecule–silicon substrate interactions leads to the formation of a large-scale 2D open supramolecular framework with improved thermal stability up to 400 K on a semiconductor surface. The robust open honeycomb network controls the growth of and serves as a template for a noncompact hexagonal fullerene array at room temperature (see picture).

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