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Manoj Kumar and Prof. Pawel M. Kozlowski A Biologically Relevant Co1+⋅⋅⋅H Bond: Possible Implications in the Protein-Induced Redox Tuning of Co2+/Co1+ Reduction Angewandte Chemie International Edition 50

Article first published online: 26 JUL 2011 | DOI: 10.1002/anie.201100469

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Reduced circumstances: A hydrogen bond induced by the Co+ ion has been identified theoretically (see picture). It plays a vital role in explaining the mechanistic base of protein-induced tuning of the Co2+/Co+ redox process, a common catalytic event in a wide variety of methyltransferases and adenosyltransferases.

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