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Prof. Dr. Sjoerd Harder, Dr. Jan Spielmann, Julia Intemann and Heinz Bandmann Hydrogen Storage in Magnesium Hydride: The Molecular Approach Angewandte Chemie International Edition 50

Version of Record online: 6 APR 2011 | DOI: 10.1002/anie.201101153

Thumbnail image of graphical abstract

Big can be small: The largest ligand-stabilized magnesium hydride cluster, containing 8 Mg2+ and 10 H ions, is a model for the smallest sub-nanometer-sized hydrogen storage material. This molecular cluster displays magnetic hydride–hydride coupling (see picture) and complete hydrogen desorption at the record-low temperature of 200 °C.

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