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Dr. Natalia B. Shustova, Dr. Igor V. Kuvychko, Dr. Alexey A. Popov, Max von Delius, Prof. Lothar Dunsch, Prof. Oren P. Anderson, Prof. Dr. Andreas Hirsch, Prof. Steven H. Strauss and Dr. Olga V. Boltalina Nitrogen Directs Multiple Radical Additions to the 9,9′-Bi-1-aza(C60-Ih)[5,6]fullerene: X-ray Structure of 6,9,12,15,18-C59N(CF3)5 Angewandte Chemie International Edition 50

Version of Record online: 29 APR 2011 | DOI: 10.1002/anie.201101227

Thumbnail image of graphical abstract

“Dixie cup” packing: Molecules of the first structurally characterized derivative of (C59N)2 bearing trifluoromethyl groups are stacked in register 10.179 Å apart to form a rare non-close-packed arrangement (AAA…; see picture). The presence of the nitrogen atom on the fullerene core results in unique addition patterns in C59N(CF3)7/9/11.

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