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Dr. Konstantin Chingin, Dr. Richard H. Perry, Dr. Steven D. Chambreau, Dr. Ghanshyam L. Vaghjiani and Prof. Richard N. Zare Generation of Melamine Polymer Condensates upon Hypergolic Ignition of Dicyanamide Ionic Liquids Angewandte Chemie International Edition 50

Article first published online: 22 JUL 2011 | DOI: 10.1002/anie.201101247

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The reaction of dicyanamide ionic liquids with nitric acid results in hypergolic ignition and the formation of a stable precipitate. The precipitate consists of cyclic triazines, including melamine and its polymers, such as melam and melem (see scheme). This study introduces a novel approach to the synthesis of cyclic azines without resorting to high temperatures and pressures.

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