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Dr. Rajendra S. Ghadwal, Prof. Dr. Herbert W. Roesky, Kevin Pröpper, Dr. Birger Dittrich, Susanne Klein and Prof. Dr. Gernot Frenking A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms Angewandte Chemie International Edition 50

Version of Record online: 13 MAY 2011 | DOI: 10.1002/anie.201101320

Thumbnail image of graphical abstract

A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:)2 (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPrCl2Si[DOUBLE BOND]NAr with KC8. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSi[DOUBLE BOND]NSiMe3)2 with three-coordinate silicon atoms.

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