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Dr. Scott G. Mitchell, Pedro I. Molina, Dr. Sumit Khanra, Dr. Haralampos N. Miras, Dr. Alessandro Prescimone, Dr. Geoffrey J. T. Cooper, Ross S. Winter, Dr. Euan K. Brechin, Dr. De-Liang Long, Prof. Richard J. Cogdell and Prof. Leroy Cronin A Mixed-Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands Angewandte Chemie International Edition 50

Version of Record online: 24 AUG 2011 | DOI: 10.1002/anie.201102727

Thumbnail image of graphical abstract

Three's a charm: The title compound (see picture, right, WO6 purple polyhedra, Mn orange and brown, Si green, O red) contains an embedded mixed-valence {Mn5O6} cubane core, which is structurally similar to the active site in photosystem II. Solid-, solution-, and gas-phase studies indicate the presence of three lacunary Keggin fragments, thereby giving insight into the complex solution chemistry of plenary POM fragments.

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