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Dr. Tianshu Li, Dr. Jelena Wiecko, Dr. Nikolay A. Pushkarevsky, Dr. Michael T. Gamer, Dr. Ralf Köppe, Prof. Sergey N. Konchenko, Prof. Dr. Manfred Scheer and Prof. Dr. Peter W. Roesky Mixed-Metal Lanthanide–Iron Triple-Decker Complexes with a cyclo-P5 Building Block Angewandte Chemie International Edition 50

Version of Record online: 31 AUG 2011 | DOI: 10.1002/anie.201102748

Thumbnail image of graphical abstract

Triple-decker complexes with mixed d/f-block metals that have a purely inorganic middle deck were unknown. A mixed-metal iron–samarium complex is presented with a cyclo-P5 polyphosphide between the metal centers (see picture; Sm large black, C small black, Fe blue, N green, O red, P pink). This compound can be obtained as either a monomer or a dimer depending on the reaction conditions.

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