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Dr. Caren Röben, Dr. José A. Souto, Yolanda González, Anton Lishchynskyi and Prof. Dr. Kilian Muñiz Enantioselective Metal-Free Diamination of Styrenes Angewandte Chemie International Edition 50

Version of Record online: 30 AUG 2011 | DOI: 10.1002/anie.201103077

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Metal-free and asymmetric: The first enantioselective diamination of styrenes simply requires a chiral hypervalent iodine(III) reagent as an oxidant and bismesylimide as a nitrogen source (see scheme, Ms=methanesulfonyl). The reaction proceeds under mild conditions and with high enantiomeric excess.

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