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Dr. Ryo Shintani, Dr. Keishi Takatsu, Momotaro Takeda and Prof. Dr. Tamio Hayashi Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates Angewandte Chemie International Edition 50

Version of Record online: 26 JUL 2011 | DOI: 10.1002/anie.201103581

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The asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronates catalyzed by a copper/N-heterocyclic carbene complex was developed and the γ-substitution products were obtained with high enantioselectivity (see scheme). To account for the observed influence of the reaction parameters a possible catalytic cycle for this process was proposed.

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