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Jiuzhao Wang, Liwei Zhao, Huimin Shi and Prof. Jing He Highly Enantioselective and Efficient Asymmetric Epoxidation Catalysts: Inorganic Nanosheets Modified with α-Amino Acids as Ligands Angewandte Chemie International Edition 50

Version of Record online: 26 AUG 2011 | DOI: 10.1002/anie.201103713

Thumbnail image of graphical abstract

Layered catalyst: The attachment of α-amino acid ligands to inorganic nanosheets for use as ligands to vanadium, resulted in a catalyst that enhanced the enantioselectivity of the epoxidation of allylic alcohols (see picture) . The catalyst can be colloidized, allowing for the catalytic reactions to be carried out under pseudo-homogeneous reaction conditions and also the catalysts to be directly recycled by simple liquid/liquid separation.

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