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Dr. Guillaume De Bo, Dr. Julien De Winter, Dr. Pascal Gerbaux and Prof. Charles-André Fustin Rotaxane-Based Mechanically Linked Block Copolymers Angewandte Chemie International Edition 50

Version of Record online: 18 AUG 2011 | DOI: 10.1002/anie.201103716

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We just clicked: A convergent approach consisting of two successive copper(I)-catalyzed azide–alkyne cycloaddition “click” reactions leads to a diblock copolymer in which the two blocks are linked by a rotaxane-type mechanical bond (see scheme). Rotaxane formation is templated by a square-planar PdII complex.

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