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Dr. Peter Höhn, Dipl.-Chem. Franziska Jach, Barış Karabiyik, Dr. Yurii Prots, Dr. Stefano Agrestini, Dr. Frank R. Wagner, Prof. Dr. Michael Ruck, Prof. Dr. Liu Hao Tjeng and Prof. Dr. Rüdiger Kniep Sr3[Co(CN)3] and Ba3[Co(CN)3]: Crystal Structure, Chemical Bonding, and Conceptional Considerations of Highly Reduced Metalates Angewandte Chemie International Edition 50

Version of Record online: 30 AUG 2011 | DOI: 10.1002/anie.201103717

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More than meets the eye: The trigonal-planar complex [Co(CN)3]6− (see structure, Co red, C gray, N green; alkaline-earth-metal counterions are yellow) has some surprises in store. The CN ligand displays variation in bond length and charge, and Co follows a closed-shell (d10) concept.

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