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Dr. Jochen Niemeyer, David A. Addy, Ian Riddlestone, Michael Kelly, Dr. Amber L. Thompson, Dr. Dragoslav Vidovic and Prof. Simon Aldridge Extending the Chain: Synthetic, Structural, and Reaction Chemistry of a BN Allenylidene Analogue Angewandte Chemie International Edition 50

Version of Record online: 11 AUG 2011 | DOI: 10.1002/anie.201103757

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α versus γ: [CpFe(CO)(PCy3)(BNCMes2)]+, synthesized by halide abstraction, represents the first example of a BN allenylidene analogue, and features an unsaturated MBNC π system. Although DFT calculations show significant LUMO amplitude at the γ (carbon) position, primary reactivity towards nucleophiles occurs at the sterically less hindered α (boron) center.

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