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Dr. George R. Whittell and Prof. Dr. Ian Manners Advances with Ammonia-Borane: Improved Recycling and Use as a Precursor to Atomically Thin BN Films Angewandte Chemie International Edition 50

Version of Record online: 1 SEP 2011 | DOI: 10.1002/anie.201103830

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BN working: Under ambient conditions, ammonia-borane (AB) dehydrogenates to polyborazylene, which, in a recent advance, can be readily regenerated in a key step for hydrogen-storage applications (see scheme). In contrast, recent reports show that dehydrogenation of AB under chemical vapor deposition conditions yields atomically thin films of hexagonal BN and their hybrids with graphene.

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