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Dipl.-Chem. Kathrin Wittstein, Dr. Kamal Kumar and Prof. Dr. Herbert Waldmann Gold(I)-Catalyzed Synthesis of Benzoxocines by an 8-endo-dig Cyclization Angewandte Chemie International Edition 50

Article first published online: 22 AUG 2011 | DOI: 10.1002/anie.201103832

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A golden dig! Gold-catalyzed direct access to functionalized 2H-1-benzoxocines, eight-membered-ring ethers, is described. This unprecedented synthesis of benzoxocines occurs by an 8-endo-dig cyclization of the 1,7-enyne substrates.

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