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Jieli He, Ting Xu, Zhihui Wang, Prof. Dr. Qinghong Zhang, Dr. Weiping Deng and Prof. Dr. Ye Wang Transformation of Methane to Propylene: A Two-Step Reaction Route Catalyzed by Modified CeO2 Nanocrystals and Zeolites Angewandte Chemie International Edition 51

Article first published online: 24 JAN 2012 | DOI: 10.1002/anie.201104071

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Propylene from methane: The transformation of methane to propylene has been realized in a two-step route via CH3Cl or CH3Br. CeO2 serves as an efficient and stable catalyst for the oxidative chlorination and bromination of methane to CH3Cl and CH3Br. In the second step, a modified zeolite is highly a selective and stable catalyst for the conversion of CH3Cl or CH3Br into propylene.

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