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Joseph M. Falkowski, Cheng Wang, Sophie Liu and Prof. Wenbin Lin Actuation of Asymmetric Cyclopropanation Catalysts: Reversible Single-Crystal to Single-Crystal Reduction of Metal–Organic Frameworks Angewandte Chemie International Edition 50

Article first published online: 8 AUG 2011 | DOI: 10.1002/anie.201104086

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To and fro: Chiral metal–organic frameworks (CMOFs) derived from redox-active ruthenium/salen building blocks exhibited reversible single-crystal to single-crystal reduction and reoxidation. The catalytically inactive RuIII CMOFs (green; see picture) were reduced to RuII CMOFs (red) that were highly active for the asymmetric cyclopropanation of alkenes with very high diastereo- and enantioselectivities.

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