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Dr. Yiming Cao, Dr. Xianxing Jiang, Luping Liu, Fangfang Shen, Futing Zhang and Prof. Dr. Rui Wang Enantioselective Michael/Cyclization Reaction Sequence: Scaffold-Inspired Synthesis of Spirooxindoles with Multiple Stereocenters Angewandte Chemie International Edition 50

Version of Record online: 25 AUG 2011 | DOI: 10.1002/anie.201104216

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A-spiro-ing: The title reaction of α-isothiocyanato imides and methyleneindolinones has been realized for the first time using 1 as the catalyst. This newly developed synthetic method provides a simple, efficient, and environmentally friendly way to access, in an enantioselective manner, densely functionalized spirooxindoles having three contiguous stereogenic centers.

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