E-mail a Wiley Online Library Link

MSc. Sebastian Bernhardt, Dr. Georg Manolikakes, MSc. Thomas Kunz and Prof. Dr. Paul Knochel Preparation of Solid Salt-Stabilized Functionalized Organozinc Compounds and their Application to Cross-Coupling and Carbonyl Addition Reactions Angewandte Chemie International Edition 50

Version of Record online: 24 AUG 2011 | DOI: 10.1002/anie.201104291

Thumbnail image of graphical abstract

Powdered organozinc reagents: Various aryl and heteroaryl bromides as well as benzylic chlorides react with Mg and Zn(OPiv)2⋅2 LiCl (OPiv=pivalate) to provide solid organozinc reagents after solvent evaporation. These powders can be stored at room temperature under argon for months and can be manipulated in air for a short time. They undergo smooth Negishi cross-coupling and carbonyl addition reactions (see scheme).

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field