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Dr. Pragna Pratic Das, Dr. Ivan L. Lysenko and Prof. Dr. Jin Kun Cha Stereoselective Alkylation of Allylic Alcohols: Tandem Ethylation and Functionalization Angewandte Chemie International Edition 50

Version of Record online: 26 AUG 2011 | DOI: 10.1002/anie.201104331

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A versatile formal SN2′ alkylation of allylic alcohols has been devised by means of the Kulinkovich reagent and in situ elaboration of the presumed alkyltitanium intermediates with electrophiles (see scheme). The utility of this method has been demonstrated in the stereoselective construction of all-carbon quaternary centers.

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