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Prof. Henri Brunner, Manfred Muschiol, Prof. Takashi Tsuno, Hyato Ike, Takaki Kurosawa and Kazuhito Koyama Change of the Fe Configuration in Chiral Half-Sandwich Complexes Within the Solvent Cage Angewandte Chemie International Edition 51

Version of Record online: 13 DEC 2011 | DOI: 10.1002/anie.201104960

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Change before exchange: Cross-over experiments with chiral half-sandwich complexes [Cp′Fe(Prophos)NCR]X (Cp′=C5H5, MeC5H4; X=I, PF6), in which change of configuration at the metal atom and RCN ligand exchange compete, show that the change of the Fe configuration within the solvent cage is faster than ligand exchange (see scheme).

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