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Ben Liu, Dr. Lu Han and Prof. Shunai Che Formation of Enantiomeric Impeller-Like Helical Architectures by DNA Self-Assembly and Silica Mineralization Angewandte Chemie International Edition 51

Version of Record online: 23 DEC 2011 | DOI: 10.1002/anie.201105445

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Impeller-like helical DNA–silica complexes (see picture; green: silica) were synthesized in the presence of magnesium ions (a). DNA chiral packing and corresponding macroscopic helical morphologies are tuned by the change of reaction temperature, pH value, and molar ratio (b) of the quaternary ammonium (yellow)/phosphate group.

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