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Dr. Yifu Yu, Jin Zhang, Xuan Wu, Weiwei Zhao and Prof. Dr. Bin Zhang Nanoporous Single-Crystal-Like CdxZn1−xS Nanosheets Fabricated by the Cation-Exchange Reaction of Inorganic–Organic Hybrid ZnS–Amine with Cadmium Ions Angewandte Chemie International Edition 51

Version of Record online: 11 OCT 2011 | DOI: 10.1002/anie.201105786

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Swapping ions: Nanoporous CdxZn1−xS nanosheets with single-crystal-like structure, good structural stability, and tunable pore size and composition have been successfully fabricated by the cation-exchange reaction of prepared ZnS–amine hybrid nanosheets with Cd2+ cations (see picture). The porous CdxZn1−xS nanosheets are highly active for photocatalytic H2 evolution from water splitting.

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