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Ramesh B. Dateer, Balagopal S. Shaibu and Prof. Dr. Rai-Shung Liu Gold-Catalyzed Intermolecular [4+2] and [2+2+2] Cycloadditions of Ynamides with Alkenes Angewandte Chemie International Edition 51

Version of Record online: 11 NOV 2011 | DOI: 10.1002/anie.201105921

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As good as gold: Gold-catalyzed intermolecular [4+2] cycloadditions of 2-arylynamides with alkenes and gold-catalyzed [2+2+2] cycloadditions of terminal ynamides with enol ethers have been developed (see scheme). The [4+2] cycloaddition is compatible with a range of alkenes and arylynamides and the [2+2+2] cycloaddition can also accommodate a variety of different arylynamide and enol ether substrates.

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