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Igor Pochorovski, Prof. Dr. Corinne Boudon, Dr. Jean-Paul Gisselbrecht, Dr. Marc-Olivier Ebert, Dr. W. Bernd Schweizer and Prof. Dr. François Diederich Quinone-Based, Redox-Active Resorcin[4]arene Cavitands Angewandte Chemie International Edition 51

Version of Record online: 14 NOV 2011 | DOI: 10.1002/anie.201106031

Thumbnail image of graphical abstract

Catch it if you can! Redox-active resorcin[4]arene cavitands with quinone walls can be reversibly reduced to the hydroquinone form, influencing their host–guest complexation strength. Specifically, a top-covered triptycenequinone cavitand forms kinetically stable complexes with cycloalkanes; this complexation is weaker in the reduced hydroquinone form.

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