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Stefanie A. Cantalupo, Stephanie R. Fiedler, Prof. Dr. Matthew P. Shores, Prof. Dr. Arnold L. Rheingold and Prof. Dr. Linda H. Doerrer High-Spin Square-Planar CoII and FeII Complexes and Reasons for Their Electronic Structure Angewandte Chemie International Edition 51

Version of Record online: 9 DEC 2011 | DOI: 10.1002/anie.201106091

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It's hip to be square: Two high-spin, square-planar {MO4} complexes are prepared, including the first molecular example with M=CoII (see structure). Structural, spectroscopic, and magnetic susceptibility characterization allows a description of the ligand features required for this highly unusual electronic structure.

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