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Dr. Kalpataru Das, Ryozo Shibuya, Yasuhito Nakahara, Nicolas Germain, Prof. Dr. Takashi Ohshima and Prof. Dr. Kazushi Mashima Platinum-Catalyzed Direct Amination of Allylic Alcohols with Aqueous Ammonia: Selective Synthesis of Primary Allylamines Angewandte Chemie International Edition 51

Version of Record online: 15 NOV 2011 | DOI: 10.1002/anie.201106737

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Direct amination of unactivated allylic alcohols with aqueous ammonia was catalyzed by a Pt/phosphine complex to give the corresponding allylamines along with water as the sole by-product. Under optimized reaction conditions, primary allylamines were obtained as major products with excellent monoallylation selectivity. cod=1,5-cyclooctadiene.

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