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Wen Si, Lei Chen, Xiao-Bo Hu, Gangfeng Tang, Zhenxia Chen, Prof. Jun-Li Hou and Prof. Zhan-Ting Li Selective Artificial Transmembrane Channels for Protons by Formation of Water Wires Angewandte Chemie International Edition 50

Version of Record online: 4 NOV 2011 | DOI: 10.1002/anie.201106857

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Lined up water molecules: Artificial transmembrane channels from pillar[5]arene monomeric and dimeric derivatives have been prepared. Single-channel conductance measurements and isotopeeffect experiments under acidic conditions showed selective proton transport through the channels, which were mediated by water wires formed in the pillar[5]arene backbones (see picture).

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