Jeonghun Kim, Dr. Chokkalingam Anand, Siddulu N. Talapaneni, Dr. Jungmok You, Prof. Salem S. Aldeyab, Prof. Eunkyoung Kim and Prof. Ajayan Vinu Catalytic Polymerization of Anthracene in a Recyclable SBA-15 Reactor with High Iron Content by a Friedel–Crafts Alkylation Angewandte Chemie International Edition 51
Ironing it out: A FeSBA-15 catalyst with a high iron content as well as a large pore diameter has been synthesized and used for the production of soluble poly(methylene anthracene) (PMAn, see scheme). The catalyst is stable, active, reusable, and affords a high yield of high-molecular-weight PMAn. The properties of the PMAns obtained can be controlled by tuning the specific surface area, pore diameter, pore volume, and Fe content of the catalysts.
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