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Jianmin Wang, Jie Chen, Choon Wee Kee and Prof. Dr. Choon-Hong Tan Enantiodivergent and γ-Selective Asymmetric Allylic Amination Angewandte Chemie International Edition 51

Version of Record online: 27 JAN 2012 | DOI: 10.1002/anie.201107317

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Double agent: The title reaction using the guanidine catalyst 1 can deliver both enantiomers of the product with excellent enantioselectivity by judicious choice of the double bond geometry of the the β,γ-unsaturated carbonyl compound. Computational studies reveal the possible origin of the inversed enantioselectivity, and the potential for enantiodivergent synthesis chiral amine-containing substrates is attractive.

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