E-mail

E-mail a Wiley Online Library Link

Dr. Hisako Hashimoto, Tetsuya Fukuda, Prof. Hiromi Tobita, Dr. Mausumi Ray and Prof. Shigeyoshi Sakaki Formation of a Germylyne Complex: Dehydrogenation of a Hydrido(hydrogermylene)tungsten Complex with Mesityl Isocyanate Angewandte Chemie International Edition 51

Version of Record online: 6 FEB 2012 | DOI: 10.1002/anie.201107501

Thumbnail image of graphical abstract

The germylyne complex 2 was obtained by dehydrogenation of a hydrido (hydrogermylene) complex 1 with mesityl isocyanate on heating. A reaction intermediate 3 was also isolated by a room temperature reaction, which was converted into 2 by heating, with elimination of MesNHCHO. A possible mechanism for the formation of 2 was elucidated by kinetic studies and DFT calculations.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH