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Dr. Hisako Hashimoto, Tetsuya Fukuda, Prof. Hiromi Tobita, Dr. Mausumi Ray and Prof. Shigeyoshi Sakaki Formation of a Germylyne Complex: Dehydrogenation of a Hydrido(hydrogermylene)tungsten Complex with Mesityl Isocyanate Angewandte Chemie International Edition 51

Version of Record online: 6 FEB 2012 | DOI: 10.1002/anie.201107501

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The germylyne complex 2 was obtained by dehydrogenation of a hydrido (hydrogermylene) complex 1 with mesityl isocyanate on heating. A reaction intermediate 3 was also isolated by a room temperature reaction, which was converted into 2 by heating, with elimination of MesNHCHO. A possible mechanism for the formation of 2 was elucidated by kinetic studies and DFT calculations.

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